Strontium titanate is a room temperature cubic perovskite with many features including quantum paraelectricity where quantum fluctuations are large enough to prevent ferroelectric order from forming (incipient ferroelectricity). A lowering of crystal symmetry occurs at ~105 K and, in Nb doped or oxygen depleted samples, superconductivity can occur with critical temperatures up to about 0.4 K at optimal doping. One possibility is that the pairing mechanism is from ferroelectric phonons and that tuning towards or away from the ferroelectric phase transition therefore affects .
Using Eliashberg strong coupling theory and assuming coupling only to one ferroelectric phonon mode, we have explored both oxygen isotope substitution and strain as means of tuning towards ferroelectricity. We predict large increases in , of 50% or more; with experimental work in qualitative agreement. Much work is yet do be done to form an accurate description for superconductivity in strontium titanate due to the low carrier densities and unknown symmetry of the superconducting order parameter.
- “Quantum Critical Origin of the Superconducting Dome in SrTiO3”
Jonathan M. Edge, Yaron Kedem, Ulrich Aschauer, Nicola A. Spaldin, and Alexander V. Balatsky
Phys. Rev. Lett. 115, 247002 (2015)
- “Superconductivity at low density near a ferroelectric quantum critical point: doped SrTiO3”
Peter Wölfle, Alexander V. Balatsky arXiv:1803.06993
- “Strain and ferroelectric soft-mode induced superconductivity in strontium titanate” K. Dunnett, Awadhesh Narayan, N. A. Spaldin, and A. V. Balatsky Phys. Rev. B 97, 144506 (2018) arXiv:1712.08368